Inflection Point Engineering Refinery Process Fundamentals Curriculum

Module 5 - FCC

Module from the Refinery Process Fundamentals Curriculum curriculum.

FLUID CATALYTIC CRACKING · Learning Objectives · 1. Explain the FCC process: riser cracking, catalyst regeneration, product fractionation 2. Describe FCC catalyst (zeolite) function and deactivation by metals/coke 3. Identify key operating variables: riser outlet temperature, cat/oil ratio, feed preheat 4. Interpret FCC yield structure: LPG, gasoline, LCO, HCO, coke 5. Understand FCC contributions to the refinery product slate and economics · FCC Process — Key Operating Parameters

Parameter Typical Range Effect of Increase Effect of Decrease Primary Control Units
Riser Outlet Temperature 960-1020°F Higher conversion, more gasoline + LPG, more coke Lower conversion, more LCO/HCO Catalyst circulation rate °F
Cat/Oil Ratio 5-8 wt/wt Higher conversion, more gasoline Lower conversion Slide valve position lb cat/lb oil
Feed Preheat Temperature 400-700°F Lower cat/oil ratio for same conversion, lower regen temp Higher cat/oil required Feed preheat exchanger/furnace °F
Feed Rate 20,000-100,000 BPD Higher throughput, lower residence time per pound Lower throughput Feed pump speed BPD
Reactor Pressure 15-30 psig Higher coke yield, lower gasoline selectivity Better selectivity, limited by blower Reactor/regen pressure balance psig
Regenerator Temperature 1250-1350°F Better coke burn, catalyst deactivation risk >1400°F Incomplete burn, CO in flue gas Coke on catalyst, air rate °F
Catalyst Activity (MAT) 65-75% Higher conversion, more gasoline Lower conversion Fresh catalyst addition rate % (microactivity test)
Residue in Feed (CCR) 0.1-3.0 wt% More coke, higher regen temp, metals deposition Cleaner operation, lower conversion Feed selection, pretreating wt%
FCC Yield Structure — Typical VGO Feed
Product Yield (vol%) Yield (wt%) Disposition Key Quality Value Driver
Fuel Gas (C1-C2) 3-5 (wt%) 3-5 Refinery fuel gas system BTU content Offsets purchased fuel
LPG (C3-C4) 12-18 10-15 Alkylation feed, propylene sales, LPG sales Propylene/propane split, C4 olefin content Propylene premium ($0.30-0.50/gal over propane)
FCC Gasoline (C5-430°F) 48-58 42-50 Gasoline blending pool RON 91-93, olefins 20-35%, sulfur Largest volume product, octane contribution
Light Cycle Oil (430-650°F) 15-25 16-26 Diesel blending (limited), ULSD hydrotreater feed High aromatics (60-80%), low cetane (20-28) Low value — poor diesel quality
Heavy Cycle Oil (650°F+) 3-8 4-10 Recycle to FCC, fuel oil blending, coker feed High aromatics, high density Low value product
Coke 4-6 (wt%) 4-6 Burned in regenerator (provides process heat) Heat of combustion ~14,000 BTU/lb Fuel for the process — not a product
Source: FOS Chief Files — Module 08 (FCC), FCC Learning folder, Examples-FCC, Cracking Catalyst Activity reference

Source: Refinery_Process_Fundamentals_Curriculum_v1.xlsx · Sheet: Module 5 - FCC