Refinery Process Fundamentals Curriculum
Module from the Refinery Process Fundamentals Curriculum curriculum.
FLUID CATALYTIC CRACKING · Learning Objectives · 1. Explain the FCC process: riser cracking, catalyst regeneration, product fractionation 2. Describe FCC catalyst (zeolite) function and deactivation by metals/coke 3. Identify key operating variables: riser outlet temperature, cat/oil ratio, feed preheat 4. Interpret FCC yield structure: LPG, gasoline, LCO, HCO, coke 5. Understand FCC contributions to the refinery product slate and economics · FCC Process — Key Operating Parameters
| Parameter | Typical Range | Effect of Increase | Effect of Decrease | Primary Control | Units |
|---|---|---|---|---|---|
| Riser Outlet Temperature | 960-1020°F | Higher conversion, more gasoline + LPG, more coke | Lower conversion, more LCO/HCO | Catalyst circulation rate | °F |
| Cat/Oil Ratio | 5-8 wt/wt | Higher conversion, more gasoline | Lower conversion | Slide valve position | lb cat/lb oil |
| Feed Preheat Temperature | 400-700°F | Lower cat/oil ratio for same conversion, lower regen temp | Higher cat/oil required | Feed preheat exchanger/furnace | °F |
| Feed Rate | 20,000-100,000 BPD | Higher throughput, lower residence time per pound | Lower throughput | Feed pump speed | BPD |
| Reactor Pressure | 15-30 psig | Higher coke yield, lower gasoline selectivity | Better selectivity, limited by blower | Reactor/regen pressure balance | psig |
| Regenerator Temperature | 1250-1350°F | Better coke burn, catalyst deactivation risk >1400°F | Incomplete burn, CO in flue gas | Coke on catalyst, air rate | °F |
| Catalyst Activity (MAT) | 65-75% | Higher conversion, more gasoline | Lower conversion | Fresh catalyst addition rate | % (microactivity test) |
| Residue in Feed (CCR) | 0.1-3.0 wt% | More coke, higher regen temp, metals deposition | Cleaner operation, lower conversion | Feed selection, pretreating | wt% |
| FCC Yield Structure — Typical VGO Feed | |||||
| Product | Yield (vol%) | Yield (wt%) | Disposition | Key Quality | Value Driver |
| Fuel Gas (C1-C2) | 3-5 (wt%) | 3-5 | Refinery fuel gas system | BTU content | Offsets purchased fuel |
| LPG (C3-C4) | 12-18 | 10-15 | Alkylation feed, propylene sales, LPG sales | Propylene/propane split, C4 olefin content | Propylene premium ($0.30-0.50/gal over propane) |
| FCC Gasoline (C5-430°F) | 48-58 | 42-50 | Gasoline blending pool | RON 91-93, olefins 20-35%, sulfur | Largest volume product, octane contribution |
| Light Cycle Oil (430-650°F) | 15-25 | 16-26 | Diesel blending (limited), ULSD hydrotreater feed | High aromatics (60-80%), low cetane (20-28) | Low value — poor diesel quality |
| Heavy Cycle Oil (650°F+) | 3-8 | 4-10 | Recycle to FCC, fuel oil blending, coker feed | High aromatics, high density | Low value product |
| Coke | 4-6 (wt%) | 4-6 | Burned in regenerator (provides process heat) | Heat of combustion ~14,000 BTU/lb | Fuel for the process — not a product |
| Source: FOS Chief Files — Module 08 (FCC), FCC Learning folder, Examples-FCC, Cracking Catalyst Activity reference |
Source: Refinery_Process_Fundamentals_Curriculum_v1.xlsx · Sheet: Module 5 - FCC
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